基于微纳层共挤技术制备多层PC/PMMA光学薄膜Preparation of Multilayer PC/PMMA Optical Films Based on Micro-Nano Layer Co-Extrusion Technology
岑少飞;张咏;张凤;
摘要(Abstract):
为制备力学性能好、高隔热性和高透光性的复合薄膜,本实验通过微纳层共挤技术,经层叠装置得到多层聚碳酸酯/聚甲基丙烯酸甲酯(PC/PMMA)光学薄膜,并对其最佳厚度值、流动和微观形态、力学性能和光学性能进行测试。结果表明:挤出温度应控制在245~260℃,两种聚合物的熔体流动速率基本相同;200μm厚度的复合薄膜平均反射率和平均透过率最高,可分别达到24.2%和82.2%。通过断面SEM分析发现:PC和PMMA两种物料层叠效果好,达到实验预期目的。加入PC后,复合薄膜的TD和MD方向上的拉伸强度和断裂伸长率均呈现较大幅度提升,说明PC形成多层复合薄膜能够显著改善PMMA力学性能。光学性能测试发现:近红外区域,PC/PMMA复合薄膜的反射率明显优于单一薄膜,200μm厚度的复合薄膜反射近红外区域的最大反射率为25.7%,平均反射率可达24%,改善光学性能效果最好。
关键词(KeyWords): 微纳层共挤技术;光学薄膜;力学性能;光学性能
基金项目(Foundation):
作者(Authors): 岑少飞;张咏;张凤;
DOI: 10.15925/j.cnki.issn1005-3360.2021.08.012
参考文献(References):
- [1]Lin J,Shi D.Photothermal and photovoltaic properties of transparent thin films of porphyrin compounds for energy applications[J].Applied Physics Reviews,2021,8(1):311-318.
- [2]李宁,孟庆林,张楠.纳米隔热复合PVB材料光热性能研究[J].新型建筑材料,2019,46(7):118-121.
- [3]Tuchinda C,Srivannaboon S,Lim H W.Photoprotection by window glass,automobile glass,and sunglasses[J].Journal of the American Academy of Dermatology,2006,54(5):845-854.
- [4]Liu H M,Young C H,Horng D J,et al.Improving the performance of a semitransparent BIPV by using high-reflectivity heat insulation film[J].International Journal of Photoenergy,2016,DOI:10.1155/2016/4174216.
- [5]Kim G H,Park J H.A PMMA optical diffuser fabricated using an electrospray method[J].Applied Physics a Materials Science&Processing,2007,86(3):347-351.
- [6]Liang H,Yang W,Jiao Z,et al.Preparation of alternating and multilayer PC/PMMA optical film[J].Engineering Plastics Application,2018,25(4):333-337.
- [7]Zhang H Q,Jin Y,Qiu Y.The optical and electrical characteristics of PMMA film prepared by spin coating method[J].IOP Conference Series Materials Science and Engineering,2015,87:12-22.
- [8]Bisen R,Tripathi J,Sharma A,et al.Optical behaviour of coumarin dye in PVA and PMMA film matrices[J].Vacuum,2018,152:65-69.
- [9]Cheng J F,Li H,Cao Z,et al.Nanolayer coextrusion:An efficient and environmentally friendly micro/nanofiber fabrication technique[J].Materials Science&Engineering C Materials for Biological Applications,2018,DOI:10.1016/j.msec.2018.11.011.
- [10]Schneider T,Colton M F,Mccauley K M,et al.Microlayer and nanolayer tubing and piping via layer multiplication coextrusion.II.rheologically mismatched systems[J].Journal of Applied Polymer Science,2020,137(20):671-681.
- [11]Cheng J F,Pu H T.Orientation of LDPE crystals from microscale to nanoscale via microlayer or manolayer coextrusion[J].Chinese Journal of Polymer Science,2016,34(12):1 411-1 422.
- [12]Kwapisz M,Knapiński M,Dyja H,et al.Analysis of the alternate extrusion and multiaxial compression process[J].Archives of Metallurgy and Materials,2015,60(1):149-152.
- [13]Lee P C,Dooley J,Robacki J,et al.Improvements in flex oxygen barrier properties of polymeric films by microlayer coextrusion[J].Journal of Plastic Film&Sheeting,2013,30(3):234-247.
- [14]Montana J S,Roland S,Miquelard G,et al.From equilibrium lamellae to out-of-equilibrium cylinders in triblock copolymer nanolayers obtained via multilayer coextrusion[J].Polymers,2017,DOI:10.1016/j.polymer.2017.12.044.
- [15]刘渝,黄安荣,韦良强,等.黏度比对EVA/PP原位微纤复合材料形态及性能的影响[J].塑料工业,2018(8):43-46.