PLA/α-生育酚抗氧化包装薄膜的制备及其性能研究Study on Preparation and Performance of PLA/α-Tocopherol Antioxidant Packaging Film
黄雅琴;
摘要(Abstract):
制备了纯聚乳酸(PLA)薄膜、特丁基对苯二酚(TBHQ)-邻苯二甲酸二辛酯(DOP)-PLA薄膜(TDP薄膜)、α-生育酚-TBHQ/DOP/PLA薄膜(αTDP薄膜)三种薄膜,并对比了三种薄膜在抗氧化性、透氧性能、水蒸气透过性、热性能和力学性能方面的差异。红外证明了纯PLA薄膜、TDP薄膜和αTDP薄膜的成功合成,三种薄膜在热重以及表面形貌方面差异不大。TDP薄膜由于TBHQ的存在而具有一定的抗氧化活性,但在添加了α-生育酚之后,αTDP薄膜抗氧化活性得到了显著的提高,能够达到89.8%。将DOP添加到纯PLA薄膜中可降低薄膜的玻璃化转变温度(Tg)。TDP薄膜和αTDP薄膜的Tg在51°C左右,而纯PLA薄膜的Tg约为67°C。将α-生育酚掺入TDP薄膜中,增加了αTDP薄膜的水蒸气透过率和断裂伸长率,降低了αTDP薄膜的透氧性,但依旧表现良好。总体来说,α-生育酚的加入能够显著提高PLA薄膜的抗氧化性且对PLA薄膜的拉伸强度影响不大,却能够有效提高薄膜的断裂伸长率。
关键词(KeyWords): 聚乳酸;α-生育酚;抗氧化;包装薄膜
基金项目(Foundation):
作者(Authors): 黄雅琴;
DOI: 10.15925/j.cnki.issn1005-3360.2021.01.021
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