芮正佳;

• 1:天津财经大学珠江学院

摘要(Abstract)：

根据生物可降解材料聚乳酸(PLA)的性能、改性方法,探索了其在3D打印包装领域的应用,为后续的改性研究和市场应用提出了新的方向。详细介绍了PLA材料的结构与特性、改性方式以及3D打印PLA材料在包装领域的应用。在保证PLA材料本身的高透明性、可降解的优势下,进一步提高其韧性、耐热性、阻隔性及导电性等,并缩减生产成本,使其在包装领域有更广泛的应用。

关键词(KeyWords)： 3D打印;聚乳酸;改性;包装领域

Abstract:

Keywords:

基金项目(Foundation):

作者(Authors): 芮正佳;

DOI: 10.15925/j.cnki.issn1005-3360.2021.04.027

参考文献(References)：

• [1]张胜,徐艳松,孙姗姗,等.3D打印材料的研究及发展现状[J].中国塑料,2016,30(1):7-14.
• [2]Chia H.Improvement of 3d printing resolution by the development of shrinkable materials[D].Los Angeles:University of California,2014.
• [3]陈彩珠,潘汉军.3D打印高分子材料研究进展[J].工程塑料应用,2016,44(9):137-140.
• [4]潘腾,朱伟,闫春泽,等.激光选区烧结3D打印成形生物高分子材料研究进展[J].高分子材料科学与工程,2016,32(3):178-183.
• [5]蔡云冰,刘志鹏,张子龙,等.聚乳酸材料在3D打印中的研究与应用进展[J].应用化工,2019,48(6):1 463-1 468.
• [6]闵玉勤,王浩仁,黄伟,等.适应3D打印技术的聚合物材料研究进展[J].粘接,2016,37(1):36-41.
• [7]Xiong Z,Ma S Q,Fan L B,et al.Surface hydrophobic modification of starch with bio-based epoxy resins to fabricate high-performance polylactide composite materials[J].Composites Science and Technology,2014,94:16-22.
• [8]瞿丽曼.聚乳酸在包装领域的发展趋势[J].上海包装,2011(2):25-27.
• [9]段瑞侠,刘文涛,陈金周,等.包装用聚乳酸的改性研究进展[J].包装工程,2019,40(5):119-126.
• [10]Basyamfar R A.Frito lay sunchips-packaging analysis[J].Jurnal Sagu,2015,13:19-26.
• [11]Said P P,Pradhan R C,Sharma N,et al.Protective coatings for shelf life extension of fruits and vegetables[J].Journal of Bioresource Engineering and Technology|Year,2014,1:1-6.
• [12]Shirai M A,Müller C M O,Grossmann M V E,et al.Adipate and citrate esters as plasticizers for poly (lactic acid)/thermoplastic starch sheets[J].Journal of Polymers and the Environment,2015,23:54-61.
• [13]何军亮,孙东成,曹艳霞,等.用于FDM的PLA共混改性[J].工程塑料应用,2017,45(6):7-11.
• [14]Burgos N,Tolaguera D,Fiori S,et al.Synthesis and characterization of lactic acid oligomers:Evaluation of performance as poly (lactic acid)plasticizers[J].Journal of Polymers and the Environment,2014,22:227-235.
• [15]Appuhamillage G,Reagan J,Khorsandi S,et al.3D printed remendable polylactic acid blends with uniform mechanical strength enabled by a dynamic Diels-Alder reaction[J].Polymer Chemistry,2017,8(13):2 087-2 092.
• [16]毕永豹,杨兆哲,许民.3D打印PLA/麦秸粉复合材料的力学性能优化[J].工程塑料应用,2017,45(4):24-28.
• [17]刘晓军,Liam D,Flynn L J,等.3D打印碳纤维增强PLA试件的力学性能分析[J].塑料,2017,46(3):47-50.
• [18]刘文杰.3D打印用改性聚乳酸线材的制备与性能研究[D].南昌:南昌航空大学,2018.
• [19]肖苏华,张静娴,张文华.应用于3D打印的聚乳酸/纳米Ti O2复合材料制备及力学性能研究[J].塑料工程学报,2017,24(3):219-224.
• [20]Chen Q,Mangadlao J D,Wallat J,et al.3D Printing biocompatible polyurethane/poly(lactic acid)/graphene oxide nanocomposites:Anisotropic properties[J].Acs Applied Materials&Interfaces,2017,9(4):4 015-4 023.
• [21]Xu W,Pranovich A,Uppstu P,et al.Novel biorenewable composite of wood polysaccharide and polylactic acid for three dimensional printing[J].Carbohydrate Polymers,2018,187:51-58.
• [22]Ambone T S,Torris A,Shanmuganathan K.Enhancing the mechanical properties of 3D printed polylactic acid using nanocellulose[J].Polymer Engineering and Science,2020,DOI:10.1002/pen.25421.
• [23]Gao Y,Li Y,Hu X R,et al.Preparation and properties of novel thermoplastic vulcanizate based on bio-based polyester/polylactic acid,and its application in 3D printing[J].Polymers,2017,DOI:10.3390/polym9120694.
• [24]Castillejos S,Cerna J,Francisco M,et al.Bulk modification of poly(lactide)(PLA) via copolymerization with poly(propylene glycol) diglycidylether(PPGDGE)[J].Polymers,2018,DOI:10.3390/polym10111184.
• [25]魏福祥.热塑性聚氨酯增韧聚乳酸3D打印耗材的制备与性能研究[D].南宁:南宁师范大学,2019.
• [26]史国涛.亚磷酸酯类扩链剂对聚乳酸的扩链稳定性研究[D].上海:华东理工大学,2015.
• [27]陈卫,汪艳,傅轶.用于3D打印的改性聚乳酸丝材的制备与研究[J].工程塑料应用,2015,43(8):21-24.
• [28]黄旭辉,赵厚华,顾建军,等.一种3D打印机用改性PLA材料的制备工艺:201410639586.6[P].2015-02-18.
• [29]Quynh T M,Mitomo H,Nagasawa N,et al.Properties of crosslinked polylactides (PLLA&PDLA) by radiation and its biodegradability[J].European Polymer Journal,2007,43(5):1 779-1 785.
• [30]Berman B.3-D printing:The new industrial revolution[J].Business Horizons,2012,55(2):155-162.
• [31]张鑫之.基于3D打印技术在文创产品设计中的开发应用[J].商业故事,2019(5):116-117.
• [32]熊小青,冯晓宁.三维打印快速原型机技术分析[J].铸造技术,2006(12):1 387-1 389.
• [33]刘梦梦,陶毓博.3D打印技术在家居摆件设计中的应用研究[J].家具与室内装饰,2019(12):24-25.
• [34]陆颖昭,徐军飞,陈宇杰,等.KH550改性对微纳纤维素/聚乳酸复合3D打印材料性能的影响[J].中国造纸学报,2019,34(2):14-19.
• [35]肖婕.冰激凌PLA保温包装结构设计及其保温性能研究[J].包装学报,2019,11(2):37-44.
• [36]刘强,曹思玮,安佰超,等.一种适于3D打印的甘蔗渣PLA复合材料及其制备方法和应用:107868417A[P].2017-10-31.
• [37]Blasko D J,Klapakis P T,Corbett J F.Training tomorrow's PLA:Amixed bag of tricks[J].China Quarterly,1996,146:488-524.
• [38]云雪艳.高韧性,高选择透过性聚乳酸薄膜的制备及其对果蔬的气调保鲜效果[D].呼和浩特:内蒙古农业大学,2017.
• [39]Kwiatkowski P,Giedrys-kalemba S,Mizieli?i?'ska M,et al.Modification of PLA foil surface by ethylcellulose and essential oils[J].Journal of Microbiology Biotechnology&Food Sciences,2016,DOI:10.15414/jmbfs.2016.5.5.440-444.
• [40]Muro-Fraguas I,Sainz-García A,Gómez P F,et al.Atmospheric pressure cold plasma anti-biofilm coatings for 3D printed food tools[J].Innovative Food Science&Emerging Technologies,2020,DOI:10.1016/j.ifset.2020.102404.
• [41]杨兆哲.杨木粉/PLA复合材料的研究及其在3D打印中的应用[D].哈尔滨:东北林业大学,2018.
• [42]Castro-Aguirre E,Iniguez-Franco F,Samsudin H,et al.Poly(lactic acid)-mass production,processing,industrial applications,and end of life[J].Advanced Drug Delivery Reviews,2016,107:333-366.